The actor providing the voice over in the Mercedes-Benz commercials from 2013 and 2014 is:
Jon Hamm IMDB
Jon Hamm is currently starring on the hit AMC television series Mad Men. In addition to Mad Men Jon has also appeared in many films and different television series such as The Town, Bridesmaids, Archer and 30 Rock. Jon Hamm has provided the voice over for Mercedes-Benz for several years, he also provides the voice for the American Airlines commercials.